Journal of the Serbian Chemical Society (Jan 2007)

Properties and efficiency of a Pt/Al2O3 catalyst applied in a solid fuel thermo-accumulating furnace

  • Belošević Srđan,
  • Mladenović Rastko,
  • Dakić Dragoljub,
  • Paprika Milijana,
  • Erić Aleksandar,
  • Đurović Dejan,
  • Komatina Mirko,
  • Grbić Boško,
  • Radić Nenad

DOI
https://doi.org/10.2298/JSC0709869B
Journal volume & issue
Vol. 72, no. 8-9
pp. 869 – 878

Abstract

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A prototype of a solid fuel thermo-accumulating furnace has been developed. In order to achieve a higher combustion efficiency, a Pt/Al2O3 catalyst in the form of 3 ± 0.3 mm spheres was applied, which enabled further combustion of flue gases within the furnace. Experimental investigation of the influence of the catalyst on the conversion of CO has been done for different operation regimes and positions of the catalyst. Paper presents selected results regarding CO emission during wood and coal combustion. Investigations suggest a considerable effect of the catalyst and a strong influence of the catalyst position to CO emission reduction. The microstructure of the catalyst beads, characterized by selective chemisorption of CO, has shown the decrease of the number of Pt sites as a consequence of blockage by coke deposits formed during the combustion of solid fuel. .

Keywords