Case Studies in Construction Materials (Dec 2024)
Study on the performance mechanism of alumina-alkali activator synergistic solidified lunar soil simulant
Abstract
The utilization of lunar in-situ resources is an important way to realize the construction and operation of Moon scientific research base. The effect of alumina-alkali activator on the mechanical properties of solidified lunar soil simulant was studied by using basaltic lunar soil simulant as raw material, adding alumina and alkali activator for solidification treatment. Characterisation of hydration products in the simulated lunar soil using X-ray diffraction (XRD), scanning electron microscopy with energy spectroscopy (SEM-EDS), fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TG-DTG) and X-ray photoelectron spectroscopy (XPS). The solidified mechanism of lunar soil simulant under the synergistic effect of alumina-alkali activator was discussed. The results showed that the compressive strength and splitting tensile strength of the solidified lunar soil simulant show an increasing trend, and the highest compressive strength was 17.29 MPa, which was 57 % greater than that of the control group. The energy evolution process inside the specimen can be divided into four stages: damage initiation, damage increase, damage mutation and damage acceleration. The incorporation of alumina can promote the geopolymerization reaction between the alkali activator and the lunar soil’s mineral composition to generate plenty of (N,C)-A-S-H gels that can fill the pores in the particles, thereby improving the mechanical strength of the solidified lunar soil simulant. Finally, the microscopic reaction mechanism model of alumina-alkali activator synergistic solidified lunar soil simulant was established.