Study on Spacing Regulation and Separation Performance of Nanofiltration Membranes of GO

Abstract

Graphene oxide (GO) membranes have attracted significant attention in the field of water processing in recent years due to their unique characteristics. However, few reports focus on both membrane stability and the “trade-off” effect. In this study, a series of aliphatic diamines (1, 2-ethylenediamine, 1, 4-butanediamine, and 1, 6-hexamethylenediamine) of covalent crosslinked GO were used to prepare diamine-modified nanofiltration membranes, BPPO/AX-GO, with adjustable layer spacing using the vacuum extraction–filtration method. Moreover, Ax-GO-modified nanofiltration membranes modified with adipose diamine had higher layer spacing, lower mass-transfer resistance, and better stability. When the number of carbon atoms was 5, the best layer spacing was reached, and when the number of carbon atoms was greater than 4, the modified membrane nanosheets more easily accumulated. With the increase in layer spacing, the water flux of the composite film increased to 26.27 L/m2·h·bar. Meanwhile, adipose diamine crosslinking significantly improved the stability of GO films. The interception sequence of different valence salts in the composite membrane was NaCl > Na2SO4 > MgSO4, and the rejection rate of bivalent salts was higher than that of monovalent salts. The results can provide some experimental basis and research ideas for overcoming the “trade-off” effect of a lamellar GO membrane.

Keywords

• graphene oxide
• layer-spacing control
• nanofiltration membrane
• separation of function