Copper-catalyzed regio- and stereo-selective hydrosilylation of terminal allenes to access (E)-allylsilanes

Abstract

Regio- and stereoselective transition-metal catalysed hydrosilylation of terminal allenes to access (E)-allylsilanes are challenging organic transformations. Herein, the authors synthesize (E)-allylsilanes via copper-catalyzed hydrosilylation of terminal allenes.