Metals (Jun 2024)
On the Problem of the Distillation Separation of Secondary Alloys of Magnesium with Zinc and Magnesium with Cadmium
Abstract
An alternative to the existing method of processing secondary magnesium raw materials by remelting in a salt furnace can be distillation separation into volatile metals (Mg, Zn and Cd), low-volatile metals (Al, Mn and Zr) and rare earth elements. The separation of metals may be tracked based on phase diagrams where the field boundaries of the vapor–liquid equilibrium are plotted. Due to the fact that Mg, Zn and Cd have comparable saturated vapor pressures, the possibility of the distillation separation of Mg–Zn and Mg–Cd systems using full state diagrams including the melt–vapor phase transition boundaries were determined in this work. The boundaries of these systems were calculated based on the partial values of saturated vapor, determined by the boiling point method, and presented in the form of temperature–concentration dependencies with the indicated boundaries. The field boundaries were calculated (L + V) at atmospheric pressure (101.33 kPa) and in vacuum (1.33 kPa and 0.7 kPa,) supposing the implementation of the process. The possibility of the separate extraction of zinc and cadmium from magnesium was considered using complete phase diagrams including the boundaries of the melt–steam phase transition. When considering the boundaries of the vapor–liquid equilibrium in the binary systems Mg–Zn and Mg–Cd, it was established that it is impossible to separate metals in one “evaporation–condensation” cycle in a vacuum of 1.33 and 0.7 kPa. The problem is caused by the small size of the fields (L + V) at the temperature, which suggests processes of the re-evaporation of the condensate from the previous distillation stage. The separation of zinc and cadmium from liquid alloys with magnesium under equilibrium conditions requires several repetitions of the condensate distillation process. In non-equilibrium conditions, the real processes will require a larger number of conversions. This implies the expediency of the joint evaporation of magnesium with zinc and cadmium and the use of condensate for additional charging to liquid magnesium, and the remainder of the distillation, where volatile metals such as Al, Mn, Zr and rare earth elements will be concentrated, should be directed to the preparation of ligatures for special magnesium-based alloys.
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