Verification of the Modified Degradation Mode Identification Technique by Employing Electrochemical Impedance Spectroscopy and Differential Voltage Analysis

Abstract

For retired automotive lithium-ion batteries, state of health (SoH) is currently utilised to grade them for a second-life application. However, researchers previously challenged this and expressed that, in addition to SoH, the actual degradation mechanism, also known as degradation mode (DM), should be considered for grading, for efficient second-life operation. To date, there is little evidence to support this. A validated DM detection technique for cell/module grading does not exist. A modified DM detection technique by tracking and indexing the incremental capacity (IC) curves was previously proposed by the authors; nevertheless, it was difficult to validate. Researchers previously proposed DM identification using Electrochemical Impedance Spectroscopy (EIS) and Differential Voltage (DV) analysis. With a direct comparison of the techniques made exploiting IC, DV, and EIS, a correlation can be made, which is presented in this article. The correlation suggests that cells identified as having the same (or different) DM by the proposed technique also identified as having the same (or different) DM growth by EIS technique proposed by other researchers. Likewise, DV analysis suggests that the DV peak’s standard deviation of similar DM cells is smaller than that of the different DM cells.

Keywords

• second-life of lithium-ion battery
• IC-DV curve
• EIS
• DM identification
• cell grading