Growing and Etching MoS2 on Carbon Nanotube Film for Enhanced Electrochemical Performance

Weiyu Xu; Qi Fang; Daobin Liu; Ke Zhang; Muhammad Habib; Chuanqiang Wu; Xusheng Zheng; Hengjie Liu; Shuangming Chen; Li Song

doi:10.3390/molecules21101318

Molecules (Sep 2016)

Growing and Etching MoS2 on Carbon Nanotube Film for Enhanced Electrochemical Performance

Weiyu Xu,
Qi Fang,
Daobin Liu,
Ke Zhang,
Muhammad Habib,
Chuanqiang Wu,
Xusheng Zheng,
Hengjie Liu,
Shuangming Chen,
Li Song

Affiliations

Weiyu Xu: National Synchrotron Radiation Laboratory, CAS Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei 230029, China
Qi Fang: National Synchrotron Radiation Laboratory, CAS Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei 230029, China
Daobin Liu: National Synchrotron Radiation Laboratory, CAS Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei 230029, China
Ke Zhang: National Synchrotron Radiation Laboratory, CAS Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei 230029, China
Muhammad Habib: National Synchrotron Radiation Laboratory, CAS Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei 230029, China
Chuanqiang Wu: National Synchrotron Radiation Laboratory, CAS Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei 230029, China
Xusheng Zheng: National Synchrotron Radiation Laboratory, CAS Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei 230029, China
Hengjie Liu: National Synchrotron Radiation Laboratory, CAS Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei 230029, China
Shuangming Chen: National Synchrotron Radiation Laboratory, CAS Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei 230029, China
Li Song: National Synchrotron Radiation Laboratory, CAS Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei 230029, China

DOI: https://doi.org/10.3390/molecules21101318
Journal volume & issue: Vol. 21, no. 10
p. 1318

Abstract

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In this work we directly synthesized molybdenum disulfide (MoS2) nanosheets on carbon nanotube film (MoS2@CNT) via a two-step chemical vapor deposition method (CVD). By etching the obtained MoS2@CNT into 10% wt HNO3, the morphology of MoS2 decorated on CNT bundles was modulated, resulting in more catalytic active MoS2 edges being exposed for significantly enhanced electrochemical performance. Our results revealed that an 8 h acid etching sample exhibited the best performance for the oxygen evolution reaction, i.e., the current density reached 10 mA/cm2 under 375 mV over-potential, and the tafel slope was as low as 94 mV/dec. The enhanced behavior was mainly originated from the more catalytic sites in MoS2 induced by the acid etching treatment and the higher conductivity from the supporting CNT films. Our study provides a new route to produce two-dimensional layers on CNT films with tunable morphology, and thus may open a window for exploring its promising applications in the fields of catalytic-, electronic-, and electrochemical-related fields.

Published in Molecules

ISSN: 1420-3049 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Science: Chemistry: Organic chemistry
Website: http://www.mdpi.com/journal/molecules

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