Enhancing Oil Recovery and Altering Wettability in Carbonate Reservoir Rocks through (3-Glycidoxypropyl)trimethoxysilane–SiO₂ Nanofluid Injection

Abstract

This study analyzes the impact of injection condition design factors of (3-glycidoxypropyl)trimethoxysilane (GPTMS)–SiO2 nanofluid on improving wettability and oil recovery through flotation and core flooding tests, respectively. Flotation tests were conducted to assess improvements in wettability that resulted from varying nanoparticle concentration, reaction time, and treatment temperature. The test results demonstrated that the hydrophilic sample ratio increased by up to 97.75% based on the nanoparticle reaction, confirming significant wettability improvement in all samples. Additionally, time-dependent fluid-flow experiments were conducted to validate oil recovery and rock–fluid interactions. In these experiments, for a 24-h reaction time, nanofluid injection caused a decrease in the maximum contact angle (43.4° from 166.5°) and a remarkable enhancement in the oil recovery rate by over 25%. Moreover, variations in contact angle and sample permeability were observed as the reaction time increased. Subsequently, the core flooding test revealed a critical reaction time of 24 h, maximizing oil recovery while minimizing permeability. Below this point in time, wettability improvement did not significantly enhance oil recovery. Conversely, beyond this threshold, additional adsorption due to particle aggregation decreased permeability, causing reduced oil recovery. Therefore, GPTMS–SiO2 nanofluid can be utilized as an injection fluid to enhance oil recovery in high-temperature and high-salinity carbonate reservoirs.

Keywords

• GPTMS
• carbonate reservoir
• enhanced oil recovery
• flotation test