Acta Crystallographica Section E (Dec 2008)
[μ-10,21-Dimethyl-3,6,14,17-tetrazatricyclo[17.3.1.18,12]tetracosa-1(23),2,6,8,10,12 (24),13,17,19,21-decaene-23,24-diolato-κ4N3,N6,O23,O24:κ4N14,N17,O23,O24]bis(perchlorato-κO)dimanganese(II)
Abstract
In the centrosymmetric and dinuclear title complex, [Mn2(C22H22N4O2)(ClO4)2], the two Mn atoms are bridged by two phenolate O atoms of the N4O2 macrocycle with an Mn...Mn distance of 2.9228 (11) Å. The distorted square–pyramidal N2O3 coordination geometry is completed by an O atom derived from a perchlorate anion.