Acta Crystallographica Section E (Dec 2008)

[μ-10,21-Dimethyl-3,6,14,17-tetrazatricyclo[17.3.1.18,12]tetracosa-1(23),2,6,8,10,12 (24),13,17,19,21-decaene-23,24-diolato-κ4N3,N6,O23,O24:κ4N14,N17,O23,O24]bis(perchlorato-κO)dimanganese(II)

  • Yi-Zhi Li,
  • Hong Zhou,
  • Zhi-Quan Pan,
  • Jing Liu

DOI
https://doi.org/10.1107/S1600536808035551
Journal volume & issue
Vol. 64, no. 12
pp. m1506 – m1506

Abstract

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In the centrosymmetric and dinuclear title complex, [Mn2(C22H22N4O2)(ClO4)2], the two Mn atoms are bridged by two phenolate O atoms of the N4O2 macrocycle with an Mn...Mn distance of 2.9228 (11) Å. The distorted square–pyramidal N2O3 coordination geometry is completed by an O atom derived from a perchlorate anion.