Adsorption of cadmium ions from simulated battery wastewater by polyethylene polyamine-modified activated carbon

Abstract

The objective of this work was to study the treatment of wastewater containing cadmium ions (Cd2+). Activated carbon (AC) was modified with potassium hydroxide (KOH) and polyethylene polyamine (PEPA). The structure and morphology of the modified AC was characterized. The effect of pH on adsorption was investigated, and the binary competitive adsorption and the reusability of the modified AC were studied. Subsequently the modified AC was used as an adsorbent for the removal of Cd2+ from wastewater. The adsorption capacity of optimized modified AC was 9.7 times that of unmodified AC. Kinetic adsorption curves were in accordance with pseudo-second-order kinetics, and the isothermal curves were in accordance with the Langmuir equation. The results indicate that the AC has potential in the treatment of the wastewater containing Cd2+ discharged from chemical plants during battery manufacturing. HIGHLIGHTS Activated carbon (AC) was modified with potassium hydroxide and polyethylene polyamine (PEPA).; The adsorption capacity of the AC for Cd2+ is up to 51.4 mg/g.; The pore size and surface group density of the AC had a good effect on the adsorption.; The AC can be employed to remove cadmium ions from simulated battery wastewater.;

Keywords

• activated carbon
• adsorption
• cadmium ion
• heavy metal
• modification
• polyethylene polyamine