Synthesis, Characterization and Photophysical Properties of Mixed Ligand (<i>η</i>³-Allyl)palladium(II) Complexes with N,N’Aromatic Diimines

Abstract

Palladium(II) complexes of the general formula [Pd(η3-C3H5)(L)](PF6), where L is 4,7-diphenyl-1,10-phenanthroline (1), 2,9-dimethyl-1,10-phenanthroline (2), 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (3), 5-methyl-1,10-phenanthroline (4), 3,4,7,8-tetramethyl-1,10-phenanthroline (5), and 2-(2′-pyridyl) quinoxaline (6), were synthesized and characterized using high-resolution ESI-MS, NMR techniques and, in the case of (6), single-crystal X-ray diffraction methods. In addition, their photophysical properties were investigated. Complexes (1)–(6) were emitted in the greenish-blue region, with those containing methyl-substituted phenanthrolines having the higher quantum yield (≈14%) in the solid state.

Keywords

• (<i>η</i>³-allyl)palladium(II)
• metal complexes
• emission spectra
• phenanthrolines