Cycle Life of Commercial Lithium-Ion Batteries with Lithium Titanium Oxide Anodes in Electric Vehicles

Abstract

The lithium titanium oxide (LTO) anode is widely accepted as one of the best anodes for the future lithium ion batteries in electric vehicles (EVs), especially since its cycle life is very long. In this paper, three different commercial LTO cells from different manufacturers were studied in accelerated cycle life tests and their capacity fades were compared. The result indicates that under 55 °C, the LTO battery still shows a high capacity fade rate. The battery aging processes of all the commercial LTO cells clearly include two stages. Using the incremental capacity (IC) analysis, it could be judged that in the first stage, the battery capacity decreases mainly due to the loss of anode material and the degradation rate is lower. In the second stage, the battery capacity decreases much faster, mainly due to the degradation of the cathode material. The result is important for the state of health (SOH) estimation and remaining useful life (RUL) prediction of battery management system (BMS) for LTO batteries in EVs.

Keywords

• lithium ion battery
• capacity fade
• incremental capacity (IC)
• lithium titanium oxide (LTO)
• electric vehicle (EV)