Frontiers in Energy Research (Feb 2018)
High Catalytic Efficiency of Lignin Depolymerization over Low Pd-Zeolite Y Loading at Mild Temperature
Abstract
This article reported a novel low-temperature process for aromatics production through lignin depolymerization catalyzed by 0.1 wt% Pd-zeolite Y catalyst prepared by a facile method. Under the same reactive condition, the as-prepared Pd-zeolite Y catalysts exhibited much higher catalytic efficiency than zeolite Y or commercial Pd/Al2O3–zeolite composites. The selectivity of the Pd-zeolite Y toward lignin depolymerization was also much higher than the other commercial zeolite-based catalysts. With the presence of hydrogen, aromatics were the predominant products with high yields of phenols and dimers (over 99%). The as-obtained aromatics can be promising feedstock for production of fuels or chemicals for various applications. Results revealed that the Pd-zeolite Y catalyst is a highly active catalyst for the cleavage of lignin interlinkages, especially the C–O–C bonds by hydrogenolysis.
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