Minería y Geología (Dec 2016)

Evaluation of kaolinite clays of Moa for the production of cement based clinker-calcined clay-limestone (LC3 )

  • Roger S. Almenares-Reyes,
  • Adrian Alujas-Díaz,
  • Lisandra Poll-Legrá,
  • Pedro R. Bassas-Noa,
  • Sergio Betancourt-Rodríguez,
  • José F. Martirena-Hernández,
  • Carlos A. Leyva-Rodríguez

Journal volume & issue
Vol. 32, no. 4
pp. 63 – 76

Abstract

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Clay materials from two outcrops of the Moa region were analyzed to determine their potential use as supplementary cementitious material in the production of ternary cements based on limestone-calcined clay. The clays were characterized by atomic absorption spectroscopy (EAA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (ATG). These methods revealed high aluminum in clays, moderate kaolinite content, a disordered structure and the presence of impurities. The solubility of aluminum and silicon in alkali and the compressive strength of LC3 systems is proportional to their content in clay, being higher for the one with higher kaolinite content and greater structural disorder (outcrop D1), although the clay of both outcrops may constitute supplementary cementitious materials in the production of ternary cements based clinker-calcined clay-limestone. The suitable thermal activation range for both clays is between 650 ° C and 850 ° C.

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