Acta Crystallographica Section E (Nov 2009)

2-Morpholino-4-oxo-4,5-dihydrothiophene-3-carbonitrile

  • JinJiang Zhu,
  • Kevin K. Liu,
  • Matthew A. Marx,
  • Arnold L. Rheingold,
  • Alex Yanovsky

DOI
https://doi.org/10.1107/S1600536809041737
Journal volume & issue
Vol. 65, no. 11
pp. o2765 – o2765

Abstract

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The title compound, C9H10N2O2S, was obtained from the treatment of ethyl 4-cyano-3-hydroxy-5-morpholinothiophene-2-carboxylate with concentrated HCl. The mean plane of the essentially planar dihydrothiophene ring is almost orthogonal to the mirror plane of the N-morpholine substituent, making a dihedral angle of 87.2 (2)°.