Photochromic samarium oxyhydride thin films

Abstract

Photochromism has been reported for several rare-earth (RE) metal oxyhydride thin films and is characterized by a reversible darkening of the sample when exposed to light with energy greater than its optical bandgap. Here, we extend the range of known photochromic RE-oxyhydrides to include samarium oxyhydrides. These SmH3−2xOx thin films are made by reactive magnetron sputtering of as-deposited SmH1.9+δ and post-oxidation in the air to the oxyhydride phase. The deposition pressure during sputtering is used to control the resultant properties of the Sm-oxyhydride film, such as the optical bandgap, cubic lattice constant, photochromic contrast, and photochromic bleaching speed. Using Sm as the RE-cation results in slower bleaching speeds compared to other lanthanides. We posit that this is due to the stability of the Sm2+ state and the difficulty to oxidizing it back to the original RE3+ state. This points to the key role of the RE-cation charge state for the optical properties of the material.