Acta Crystallographica Section E (Jan 2011)

Dichlorido(N,N′-diisopropylpiperidine-1-carboximidamidato-κ2N,N′)titanium(IV)

  • Li-Ying Shi,
  • Zhen-Qin Zhang,
  • Yong Zhang,
  • Ying-Ming Yao,
  • Mei Wang

DOI
https://doi.org/10.1107/S1600536810053262
Journal volume & issue
Vol. 67, no. 1
pp. m125 – m125

Abstract

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In the mononuclear title complex, [Ti(C12H24N3)2Cl2], the TiIV ion, located on a crystallographic inversion center, is six-coordinated by four N atoms from two N′,N′′-diisopropyl-N-carboxamidine anions and two chloride atoms in a distorted octahedral geometry. The dihedral angles between the piperidine groups and the NCN chelate rings are 51.5 (1) and 52.3 (1)°.