Acta Crystallographica Section E (Jan 2011)
Dichlorido(N,N′-diisopropylpiperidine-1-carboximidamidato-κ2N,N′)titanium(IV)
Abstract
In the mononuclear title complex, [Ti(C12H24N3)2Cl2], the TiIV ion, located on a crystallographic inversion center, is six-coordinated by four N atoms from two N′,N′′-diisopropyl-N-carboxamidine anions and two chloride atoms in a distorted octahedral geometry. The dihedral angles between the piperidine groups and the NCN chelate rings are 51.5 (1) and 52.3 (1)°.