Insight into the Effect of Oxygen Vacancy Prepared by Different Methods on CuO/Anatase Catalyst for CO Catalytic Oxidation

Abstract

In this study, CuO loaded on anatase TiO2 catalysts (CuO/anatase) with oxygen vacancies was synthesized via reduction treatments by NaHB4 and H2 (CuO/anatase-B, CuO/anatase-H), respectively. The characterizations suggest that different reduction treatments bring different concentration of oxygen vacancies in the CuO/anatase catalysts, which finally affect the CO catalytic performance. The CuO/anatase-B and CuO/anatase-H exhibit CO conversion of 90% at 182 and 198 °C, respectively, which is lower than what occurred for CuO/anatase (300 °C). The XRD, Raman, and EPR results show that the amount of the oxygen vacancies of the CuO/anatase-H is the largest, indicating a stronger reduction effect of H2 than NaHB4 on the anatase surface. The in situ DRIFTS results exhibit that the Cu sites are the adsorption sites of CO, and the oxygen vacancies on the anatase can active the O2 molecules into reactive oxygen species. According to the in situ DRIFTS results, it can be concluded that in the CO oxidation reaction, only the CuO/anatase-H catalyst can be carried out by the Mvk mechanism, which greatly improves its catalytic efficiency. This study explained the reaction mechanisms of CO oxidation on various anatase surfaces, which offers detailed insights into how to prepare suitable catalysts for low-temperature oxidation reactions.

Keywords

• CuO/anatase
• H₂ reduction treatment
• oxygen vacancies
• CO catalytic oxidation
• CO reaction mechanism