Nature Communications (May 2021)

Degradation mechanism of hybrid tin-based perovskite solar cells and the critical role of tin (IV) iodide

  • Luis Lanzetta,
  • Thomas Webb,
  • Nourdine Zibouche,
  • Xinxing Liang,
  • Dong Ding,
  • Ganghong Min,
  • Robert J. E. Westbrook,
  • Benedetta Gaggio,
  • Thomas J. Macdonald,
  • M. Saiful Islam,
  • Saif A. Haque

DOI
https://doi.org/10.1038/s41467-021-22864-z
Journal volume & issue
Vol. 12, no. 1
pp. 1 – 11

Abstract

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Tin perovskites have emerged as promising alternatives to toxic lead perovskite in next-generation photovoltaics, but the poor environmental stability remains an obstacle for the application. Here, the authors study the degradation mechanism of tin perovskite films, and identify a cyclic degradation mechanism involving tin (IV) iodide.