Acta Crystallographica Section E (Oct 2011)

(7R,8S,9S,12S)-1-Benzyloxy-13,14-didehydro-12-hydroxy-2,13-dimethoxy-N-methylmorphinane

  • Ai-Shun Ding,
  • Hong-Sheng Gao,
  • Dan Luo,
  • Ning-Fei Jiang,
  • Xing-Liang Zheng

DOI
https://doi.org/10.1107/S1600536811037226
Journal volume & issue
Vol. 67, no. 10
pp. o2662 – o2663

Abstract

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In the title compound, C26H31NO4, a sinomenine derivative, the angle between the two aromatic rings is 53.34 (4)°. The N-containing ring is in a chair conformation, while the other two non-planar rings are in a half-boat conformation. In the crystal, molecules are linked by O—H...N interactions into a C(8) chain along [100].