Science of Sintering (Jan 2012)

SiC synthesis using natural Mg-silicates

  • Devečerski A.,
  • Pošarac M.,
  • Dimitrijević M.,
  • Rosić M.,
  • Volkov-Husović T.,
  • Branković G.

DOI
https://doi.org/10.2298/SOS1201081D
Journal volume & issue
Vol. 44, no. 1
pp. 81 – 94

Abstract

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The silicon carbide powders are prepared by carbothermal reduction of domestic mineral resources (white and brown sepiolite), at relatively low temperatures (1200 - 1600oC). Carbothermal reduction process is greatly influenced by chemical composition of sepiolites and type of carbon used. Obtained SiC powders consist of fine β-SiC particles and did not retain the fibrous morphology of sepiolites. Catalytical influence of Fe is attributed to formation of iron-silicide and its potentionaly important role in removal of Mg-species, i.e. reduction of Mg2SiO4 and MgO into Mg(g).

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