Photoredox-catalyzed C–C bond cleavage of cyclopropanes for the formation of C(sp 3)–heteroatom bonds

Liang Ge; Chi Zhang; Chengkai Pan; Ding-Xing Wang; Dong-Ying Liu; Zhi-Qiang Li; Pingkang Shen; Lifang Tian; Chao Feng

doi:10.1038/s41467-022-33602-4

Nature Communications (Oct 2022)

Photoredox-catalyzed C–C bond cleavage of cyclopropanes for the formation of C(sp 3)–heteroatom bonds

Liang Ge,
Chi Zhang,
Chengkai Pan,
Ding-Xing Wang,
Dong-Ying Liu,
Zhi-Qiang Li,
Pingkang Shen,
Lifang Tian,
Chao Feng

Affiliations

Liang Ge: Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech University
Chi Zhang: Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech University
Chengkai Pan: Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech University
Ding-Xing Wang: Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech University
Dong-Ying Liu: Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech University
Zhi-Qiang Li: Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech University
Pingkang Shen: Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech University
Lifang Tian: Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech University
Chao Feng: Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech University

DOI: https://doi.org/10.1038/s41467-022-33602-4
Journal volume & issue: Vol. 13, no. 1
pp. 1 – 13

Abstract

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The development of new methodologies for the construction of C(sp 3)–heteroatom bonds under mild conditions is desirable. Here the authors report the formation of C(sp 3)–heteroatom bonds via ring opening of arylcyclopropanes enabled by photoredox catalysis.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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