Composite Carbon Foams as an Alternative to the Conventional Biomass-Derived Activated Carbon in Catalytic Application

Abstract

The suitability of a new type of polyurethane-based composite carbon foam for several possible usages is evaluated and reported. A comparison of the properties of the as-prepared carbon foams was performed with widely available commercial biomass-derived activated carbon. Carbon foams were synthesized from polyurethane foams with different graphite contents through one-step activation using CO2. In this work, a carbon catalyst was synthesized with a moderately active surface (SBET = 554 m2/g), a thermal conductivity of 0.09 W/mK, and a minimum metal ion content of 0.2 wt%, which can be recommended for phosgene production. The composite carbon foams exhibited better thermal stability, as there is a very little weight loss at temperatures below 500 °C, and weight loss is slower at temperatures above 500 °C (phosgene synthesis: 550–700 °C). Owing to the good surface and thermal properties and the negligible metallic impurities, composite carbon foam produced from polyurethane foams are the best alternative to the conventional coconut-based activated carbon catalyst used in phosgene gas production.

Keywords

• carbon foam
• phosgene
• catalyst
• biomass-derived activated carbon
• specific surface area
• pore size distribution