Acta Crystallographica Section E (May 2012)

Diaquabis(1-methyl-1H-imidazole-κN3)bis[2-(naphthalen-1-yl)acetato-κO]cobalt(II)

  • Fu-Jun Yin,
  • Li-Jun Han,
  • Xing-You Xu,
  • Hong Zhao

DOI
https://doi.org/10.1107/S1600536812013505
Journal volume & issue
Vol. 68, no. 5
pp. m533 – m533

Abstract

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In the title compound, [Co(C12H9O2)2(C4H6N2)2(H2O)2], the CoII ion is located on an inversion centre and displays a distorted octahedral coordination geometry. Two O atoms from two water molecules and two carboxylate O atoms from two 2-(naphthalen-1-yl)acetate ligands are in the equatorial plane and two N atoms from two 1-methyl-1H-imidazole ligands are in the axial positions. The structure is stabilized by intramolecular O—H...O hydrogen bonds. Intermolecular O—H...O hydrogen bonds link the complex molecules into chains along [100].