LOW-TEMPERATURE OZONE DECOMPOSITION BY COMPLEXES OF Cu(II), Co(II) AND Mn(II) WITH HEXAMETHYLENETETRAMINE

Abstract

First, the complexes MCl2*HTMA*xH2O/SiO2 (M = Cu(II), Co(II), Mn(II)) with hexa-methylenetetramine (HMTA) molecule weakly bound with a central M atom (CM ranging from 5.010-7 to 5.010-6 mol/g) have been found to catalyse the ozone decomposition. Their activity and turnover number exceeded much those for MCl2*хН2О/ SiO2 acido complexes

Keywords

• металокомплекси, гексаметилентетрамін, каталізатор, озон, розклад