L-asparagine Assisted Synthesis of Pt/CeO₂ Nanospheres for Toluene Combustion

Abstract

Pt1/CeO2 nanospheres (Pt/CeO2-NS) were synthesized by the bath oiling method with L-asparagine as a necessary additive. Owing to the morphology control effect and coordination interaction of L-asparagine, CeO2 nanospheres can retain their nanosphere structure and show stronger electronic metal-support interaction with highly dispersed Pt. Moreover, the toluene catalytic combustion performance of Pt/CeO2-NS was investigated. The structure-performance relationship is analyzed according to the coordination state of Pt. The Pt/CeO2-NS catalyst exhibited superior catalytic activity than the commercial CeO2-supported Pt catalyst, which is attributed to its higher oxygen vacancy and Pt4+.

Keywords

• toluene
• catalytic combustion
• highly dispersed Pt
• L-asparagine
• ceria