Green Synthesis and Catalysis (May 2024)
Rh(II) catalyzed efficient sigmatropic rearrangement reaction of pyridotriazoles and sulfides
Abstract
The [2,3]- and [1,2]-sigmatropic rearrangement reactions between pyridotriazoles and sulfides catalyzed by rhodium(II) were investigated. The utilization of pyridotriazoles as the carbene precursors in this kind of reaction efficiently constructed the C(sp3)-S and C(sp3)-Se bond with broad substrate scope and great functional group tolerance.