Complex processing of titanium-rare metal raw material

Abstract

The paper is devoted to investigation of the complex processing of titanium-rare metal raw materials with ammonium hydrodifluoride. It is stated that fluorination of the main components of the mineral raw materials with ammonium hydrodifluoride proceeds with formation of complex ammonium fluorometallates and simple fluorides. It is showed that in the process of aqueous leaching of the fluorinated mineral raw material niobium and tantalum completely pass into solution together with titanium, iron, and silicon fluoroammonium salts while all the rare-earth elements stay in the insoluble residue as complex fluorosodium salts together with CaF2. The method of separation of the fluoroammonium salts with obtaining marketable products and isolation of the rare-earth elements from the insoluble residue is offered.