Synthesis, characterization, and performance of chitosan/nylon 6/polyurethane blend for the removal of chromium (VI) and lead (II) ions from aqueous solutions for enhanced kinetic adsorption studies

Abstract

Adsorption is vital for the elimination of Cr6+ and Pb2+ ions in the contaminated solution medium. A ternary blend made up of chitosan, nylon 6 and polyurethane foam (CS/Ny 6/PUF) blend in the ratio of 2:1:1 has been investigated. These blends are used as an adsorbent due to the insoluble nature in acidic and basic medium. The adsorption efficacy was analyzed by modifying pH, contact time, and adsorbent dosage. The maximum uptake of metal ions has been exhibited in the pH range 5. An equilibrium adsorption statistic indicated that adsorption isotherm follows the Freundlich model. The adsorption kinetic parameters specified that the adsorption of chromium has shown pseudo-second-order and lead pseudo-first-order reaction. HIGHLIGHTS CS/NY 6/PUF blends adsorption efficacy was analyzed by modifying pH.; Contact time, and adsorbent dosage.; Langmuir and Freundlich adsorption isotherm was utilized.; An adsorption harmony of metal particles was adsorbed by the adsorbent.; The adsorption of chromium and lead ions exhibits pseudo-second-order and pseudo-first-order kinetic reaction.;

Keywords

• chitosan
• freundlich
• langmuir
• nylon 6
• polyurethane foam