Nature Communications (Feb 2020)

Elucidating the mechanism of heterogeneous Wacker oxidation over Pd-Cu/zeolite Y by transient XAS

  • Jerick Imbao,
  • Jeroen A. van Bokhoven,
  • Adam Clark,
  • Maarten Nachtegaal

DOI
https://doi.org/10.1038/s41467-020-14982-x
Journal volume & issue
Vol. 11, no. 1
pp. 1 – 9

Abstract

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Unlike the homogeneous Wacker process, understanding of the mechanism of the heterogeneous system remains superficial. Here, the authors investigate the mechanism of heterogeneous Wacker oxidation over Pd-Cu/zeolite Y through the synergistic combination of kinetic, spectroscopic and chemometric studies.