Corchorus Olitorius-Mediated Green Synthesis and Characterization of Nickel and Manganese Ferrite Nanoparticles

Abstract

Developing a method for preparing Ni and Mn ferrites was the main objective of this study due to the importance of these materials in high-frequency applications. These ferrites were made by assisting combustion with dried leaves of Corchorus olitorius and then heating them to 700 °C. Several methods, including FTIR, XRD, TEM, and SEM/EDX, were used to characterize these ferrites. The thermal behavior, surface and magnetic properties of the as-prepared materials were determined. The results revealed that the method used is cheap, economical, environmentally friendly and makes it easy to produce the studied ferrites. FTIR, XRD, TEM, and SEM/EDX analyses show the formation of nanocrystalline ferrites with brittle, spongy and spinel-type structures, having two main vibration bands located around 400 cm−1 and 600 cm−1. However, TG-DTG results display the thermal behavior of different materials which consisted of unreacted oxides, carbon and the corresponding ferrites in the range of 300 °C to 600 °C. Moreover, complete conversion of the unreacted oxides to the equivalent ferrite was achieved by increasing heat treatment from 600 °C to 1000 °C. Ferrites are heated at 700 °C, which reduces their surface area. The magnetic properties of different ferrites calcined at 700 °C were estimated using the VSM technique. The magnetism of Fe-based materials containing Ni and Mn is 12.189 emu/g and 25.988 emu/g, respectively. Moreover, the squareness and coercivity of Ni ferrite are greater than for Mn ferrite.

Keywords

• XRD
• FTIR
• squareness
• magnetization
• ferrites