Hydrolysis of Element (White) Phosphorus under the Action of Heterometallic Cubane-Type Cluster {Mo3PdS4}

Airat M. Kuchkaev; Nikita Y. Shmelev; Aidar M. Kuchkaev; Aleksandr V. Sukhov; Vasily M. Babaev; Khasan R. Khayarov; Artem L. Gushchin; Maxim N. Sokolov; Oleg G. Sinyashin; Dmitry G. Yakhvarov

doi:10.3390/molecules26030538

Molecules (Jan 2021)

Hydrolysis of Element (White) Phosphorus under the Action of Heterometallic Cubane-Type Cluster {Mo3PdS4}

Airat M. Kuchkaev,
Nikita Y. Shmelev,
Aidar M. Kuchkaev,
Aleksandr V. Sukhov,
Vasily M. Babaev,
Khasan R. Khayarov,
Artem L. Gushchin,
Maxim N. Sokolov,
Oleg G. Sinyashin,
Dmitry G. Yakhvarov

Affiliations

Airat M. Kuchkaev: Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Nikita Y. Shmelev: Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Aidar M. Kuchkaev: Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Aleksandr V. Sukhov: Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Vasily M. Babaev: Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Khasan R. Khayarov: Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kremlyovskaya Str. 18, 420008 Kazan, Russia
Artem L. Gushchin: Nikolaev Institute of Inorganic Chemistry SB RAS Lavrentiev av. 3, 630090 Novosibirsk, Russia
Maxim N. Sokolov: Nikolaev Institute of Inorganic Chemistry SB RAS Lavrentiev av. 3, 630090 Novosibirsk, Russia
Oleg G. Sinyashin: Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Dmitry G. Yakhvarov: Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia

DOI: https://doi.org/10.3390/molecules26030538
Journal volume & issue: Vol. 26, no. 3
p. 538

Abstract

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Reaction of heterometallic cubane-type cluster complexes—[Mo3{Pd(dba)}S4Cl3(dbbpy)3]PF6, [Mo3{Pd(tu)}S4Cl3(dbbpy)3]Cl and [Mo3{Pd(dba)}S4(acac)3(py)3]PF6, where dba—dibenzylideneacetone, dbbpy—4,4′-di-tert-butyl-2,2′-bipyridine, tu—thiourea, acac—acetylacetonate, py—pyridine, with white phosphorus (P4) in the presence of water leads to the formation of phosphorous acid H3PO3 as the major product. The crucial role of the Pd atom in the cluster core {Mo3PdS4} has been established in the hydrolytic activation of P4 molecule. The main intermediate of the process, the cluster complex [Mo3{PdP(OH)3}S4Cl3(dbbpy)3]+ with coordinated P(OH)3 molecule and phosphine PH3, have been detected by 31P NMR spectroscopy in the reaction mixture.

Published in Molecules

ISSN: 1420-3049 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Science: Chemistry: Organic chemistry
Website: http://www.mdpi.com/journal/molecules

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