The growth evolution of SnSe-doped SnTe alloy by in-situ selenization substitution method

Abstract

In the era of increasing environmental pollution and energy crisis, the development of thermoelectric materials to achieve the reuse of waste heat energy is of great significance. SnTe, as an environmentally friendly thermoelectric material, its high electronic-thermal conductivity and coupled high electrical conductivity originated from intrinsic high carrier hole concentration leads to the unsatisfactory thermoelectric properties. With a lot of research going on to optimize thermoelectric performance by decoupling the thermo-electrical contradiction, the entropy engineering strategy, which can independently modulate lattice thermal conductivity is proved to be feasible by increasing the internal configurational entropy through doping. However, due to the uncontrollable growth microscopic process and the perturbation of film quality, the desired precise phase doping remains a challenge. In this work, we report an instantiation of the entropy increase of SnSe-doped SnTe alloy thin films prepared by two-step magnetron sputtering and selenization method. The microstructure and physical properties of thin films were investigated for replaying and controlling the growth evolution of in-situ selenization substitution. When the reaction temperature and duration were adjusted to 300℃ and 30 mins respectively, the desired pure phase doping was obtained. This work provides a new method of doping modification of SnTe materials, and the product as a new functional material expands the thermoelectric material library. In particular, it has positive reference significance for the development of synthesis controllability and structure establishment of complex polycrystalline materials.

Keywords

• Magnetron sputtering growth
• In-situ selenization substitution
• Tin telluride alloy
• Stannic selenide
• Material synthesis