Polyol Synthesis of Ag-Doped Copper Oxide Nanoparticles as a Methylene Blue-Degrading Agent

Abstract

The use of metal oxide nanomaterials as photocatalysts for wastewater treatment has received significant attention in recent years due to their unique physicochemical properties. In this study, we use a polyol-mediated refluxing method to synthesize silver-incorporated copper oxide nanomaterials (Ag@CuO NMs). The use of tetra butyl ammonium bromide (TBAB) as a capping agent and ethylene glycol as a reducing agent for Ag+ to Ag is elaborated upon. The prepared Ag@CuO NMs were tested for their ability to degrade water pollutants, specifically methylene blue (MB) dye. Two different Ag contents, weights of 3% and 5%, were used to produce modified CuO-based nanomaterials. The crystalline structures of the NMs were characterized via XRD diffraction, and the morphology of the materials was investigated using FE-SEM. The optical properties were studied using UV-vis spectroscopy. The photocatalytic activity of the Ag@CuO NMs was evaluated by analyzing the degradation of MB dye when exposed to UV-visible light. Our results showed that the 5% weight Ag@CuO NM sample exhibited the most efficient degradation activity against MB dye. Therefore, these nanomaterials hold potential for photocatalytic applications, particularly for wastewater purification.

Keywords

• methylene blue
• photocatalytic activity
• refluxing method
• Ag@CuO Ns