Acta Crystallographica Section E (Jun 2013)

{N,N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl]methylamine-κ2P,P′}bis(η5-cyclopentadienyl)titanium(II)

  • Martin Haehnel,
  • Sven Hansen,
  • Anke Spannenberg,
  • Torsten Beweries

DOI
https://doi.org/10.1107/S1600536813014244
Journal volume & issue
Vol. 69, no. 6
pp. m346 – m346

Abstract

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The title compound, [Ti(C5H5)2(C9H11F12NO4P2)], is a four-membered titanacycle obtained from the reaction of Cp2Ti(η2-Me3SiC2SiMe3) and CH3N[P(OCH2CF3)2]2 {N,N-bis[bis(trifluoroethoxy)phosphanyl]methylamine, tfepma}. The TiII atom is coordinated by two cyclopentadienyl (Cp) ligands and the chelating tfepma ligand in a strongly distorted tetrahedral geometry. The molecule is located on a mirror plane.