Preparation of HxPO4(3-x)- Imprinted Polypyrrole Membrane Material and Its Electrochemically Switched Ion Exchange Properties

Lifang XING; Qinbo YUAN; Liang CHEN; Xianxian ZHOU; Yu LI; Enzhi WANG; Panpan LIU; Shibin LIU

doi:10.16355/j.cnki.issn1007-9432tyut.2021.03.007

Taiyuan Ligong Daxue xuebao (May 2021)

Preparation of HxPO4(3-x)- Imprinted Polypyrrole Membrane Material and Its Electrochemically Switched Ion Exchange Properties

Lifang XING,
Qinbo YUAN,
Liang CHEN,
Xianxian ZHOU,
Yu LI,
Enzhi WANG,
Panpan LIU,
Shibin LIU

Affiliations

Lifang XING: College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China
Qinbo YUAN: State Key Laboratory of Hydroscience and Engineering, Tsinghua University, Beijing 100084, China
Liang CHEN: College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China
Xianxian ZHOU: College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China
Yu LI: College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China
Enzhi WANG: State Key Laboratory of Hydroscience and Engineering, Tsinghua University, Beijing 100084, China
Panpan LIU: College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China
Shibin LIU: College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China

DOI: https://doi.org/10.16355/j.cnki.issn1007-9432tyut.2021.03.007
Journal volume & issue: Vol. 52, no. 3
pp. 374 – 381

Abstract

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The polypyrrole-based imprinted membrane material was prepared on gold plated quartz wafer by potentiostatic method. The morphology, structure, and composition of membrane material were characterized by SEM, FT-IR, and XPS. The results show that the surface micromorphology of material was cauliflower-like, and the membrane contained H2PO4-, which had the characteristics of H2PO4- imprinting. The exchange properties of HxPO4(3-x)- were investigated by electrochemical method. The results show that with the increase of pH, the ion exchange capacity first decreased and then increased, showing a “V” shape. As the concentration of NaH2PO4 increased, the ion exchange capacity monotonously increased, up to 150 mg/g.

Published in Taiyuan Ligong Daxue xuebao

ISSN: 1007-9432 (Print)
Publisher: Editorial Office of Journal of Taiyuan University of Technology
Country of publisher: China
LCC subjects: Technology: Chemical technology: Chemical engineering; Technology: Electrical engineering. Electronics. Nuclear engineering: Materials of engineering and construction. Mechanics of materials
Website: https://tyutjournal.tyut.edu.cn/english.html

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