Diazidobis[2,4-diamino-6-(2-pyridyl)-1,3,5-triazine-κ2N1,N6]zinc(II)

Abstract

In the title mononuclear complex, [Zn(N3)2(C8H8N6)2], the ZnII atom, lying on a twofold rotation axis, is six-coordinated in a distorted octahedral environment by four N atoms from two 2,4-diamino-6-(2-pyridyl)-1,3,5-triazine ligands and two N atoms from two end-on-coordinated azide ions. N—H...N hydrogen bonds between the ligand and azide ion link the complex molecules into a three-dimensional network.