Acta Crystallographica Section E (Feb 2014)

1,3,5-Tri-p-tolylpentane-1,5-diol

  • A. Thiruvalluvar,
  • R. Chithiravel,
  • S. Muthusubramanian,
  • R. J. Butcher

DOI
https://doi.org/10.1107/S160053681400018X
Journal volume & issue
Vol. 70, no. 2
pp. o122 – o123

Abstract

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In the title compound, C26H30O2, the central benzene ring forms dihedral angles of 14.85 (15) and 28.17 (14)° with the terminal benzene rings. The dihedral angle between the terminal benzene rings is 32.14 (13)°. The crystal packing exhibits two strong intermolecular O—H...O hydrogen bonds, forming directed four-membered co-operative rings. A region of disordered electron density, most probably disordered ethyl acetate solvent molecules, occupying voids of ca 519 Å3 for an electron count of 59, was treated using the SQUEEZE routine in PLATON [Spek (2009). Acta Cryst. D65, 148–155]. Their formula mass and unit-cell characteristics were not taken into account during refinement. The structure was refined as an inversion twin [absolute structure parameter = −0.3 (4)].