Carbon Energy (Jul 2023)

Deciphering the degradation discrepancy in Ni‐rich cathodes with a diverse proportion of [003] crystallographic textures

  • Lang Qiu,
  • Mengke Zhang,
  • Yang Song,
  • Zhenguo Wu,
  • Yan‐Fang Zhu,
  • Jun Zhang,
  • Dong Wang,
  • Hai‐Yan Hu,
  • Hong‐Wei Li,
  • Hang‐Rui Liu,
  • Xin‐Bei Jia,
  • Jian Peng,
  • Shuangqiang Chen,
  • Zuguang Yang,
  • Yao Xiao,
  • Xiaodong Guo

DOI
https://doi.org/10.1002/cey2.298
Journal volume & issue
Vol. 5, no. 7
pp. n/a – n/a

Abstract

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Abstract The crystal plane plays a very important role in the properties of Ni‐rich cathodes. [003] crystallographic texture regulation has been proven to improve structural stability, and yet, the discrepancy of particles with different exposed ratios of [003] in structural attenuation has not been clarified. Herein, we have unraveled comprehensively the structural decay difference for Ni‐rich cathodes’ primary particles with the different percentages of exposed [003] by regulating the precursor coprecipitation process. The findings based on structural characterization, first‐principles calculations, finite element analysis, and electrochemical test reveal that the length and width of particles represent [11¯0] $[1ar{1}0]$ and [003] directions, respectively, and show that cathode particles with a higher [11¯0] $[1ar{1}0]$/[003] ratio can effectively inhibit structure degradation and intergranular/intragranular crack formation owing to the low oxygen vacancy formation energy on (003) planes and the small local stress on secondary/primary particles. This study may provide guidance for the structural design of layered cathodes.

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