Structural Characterization and Adsorption Capability of Carbonaceous Matters Extracted from Carbonaceous Gold Concentrate

Abstract

In this paper, the structures of element carbon and humic acid extracted from carbonaceous gold concentrate were characterized employing a variety of analytical methods. The extracted amounts of ECE (elemental carbon extract) and HAE (humic acid extract) were 14.84–38.50 and 11.55–28.05 mg g−1, respectively. SEM and porosity analysis indicated that ECE occurred mostly as irregular blocky particles with a mesoporous surface with the average pore diameter being 31.42 nm. The particle size of ECE was mainly ranged from 5.5 to 42 μm and the specific surface area was 20.35 m2 g−1. The physicochemical features and structure of ECE were close to activated carbon, and the crystallinity was slightly lower than graphite. The particle size distribution of HAE varied from 40 to 400 nm with the specific surface area of 42.84 m2 g−1, whereas the average pore diameter of HAE was 2.97 nm. FTIR and UV–VIS analyses indicated that HAE was a complex organic compound containing the enrichment of oxygen-containing structure. The results showed that the adsorption amounts of ECE and HAE under the acidic conditions were 470.46 and 357.60 mg g−1, respectively. In an alkaline environment, the amount of ECE was 449.02 mg g−1 and the value of HAE was 294.72 mg g−1. ECE mainly utilized the outer surface and mesoporous structure to adsorb gold, while the functional groups’ complexation or surface site adsorption was the leading approach for HAE to adsorb gold.

Keywords

• carbonaceous gold concentrate
• carbonaceous matters
• elemental carbon
• humic acid
• structural characterization
• adsorptive capacity