Utilizing the lignocellulosic fibers from Pineapple Crown Leaves extract for enhancing TiO2 interfacial bonding in dye-sensitized solar cell photoanodes

Abstract

Abstract The crown leaves of pineapple possess a wealth of smooth and glossy silk medium-length fibers, primarily composed of cellulose and lignin, accompanied by constituents such as fats, waxes, pectin, uronic acid, anhydride, pentosan, color pigments, and inorganic substances. These fibers exhibit an anisotropic nature and are characterized by hydrogen bonding interactions, rendering them effective in conjunction with semiconductor oxide (TiO2) through their cellulosic fibrils. The dye extracted from Pineapple Crown Leaves (PCL) using ethanol was subjected to FTIR and UV–visible spectroscopy. The FTIR analysis revealed absorption peaks at 3268 cm−1 and 2922 cm−1, confirming the presence of –OH and –CH stretching attributed to the fibrils within the dye. UV–visible spectroscopy further demonstrated absorption within the visible region of the electromagnetic spectrum. Additionally, a photoluminescence study of the dye showcased emission within the visible range of the electromagnetic spectrum. Subsequently, a solar cell incorporating this dye underwent JV characterization, yielding an efficiency of 1.0034%, along with fill factor, open-circuit voltage, and short-circuit current density values of 0.40644, 0.7058 V, and 3.4906 mA/cm2, respectively. To gain deeper insights and facilitate optimization for large-scale installations, a simulation model utilizing PC1D was proposed to explore the influential parameters of the Dye-sensitized solar cell (DSSC).

Keywords

• Cellulosic fibrils
• Electron injection
• Simulation
• Hydrogen bonding