Temperature-independent non-linear terahertz transmission by liquid water

Abstract

Liquid water is one of the most studied substances, yet many of its properties are difficult to rationalize. The uniqueness of water is rooted in the dynamic network of hydrogen-bonded molecules with relaxation time constants of about one picosecond. Terahertz fields oscillate on a picosecond timescale and are inherently suited to study water. Recent advances in non-linear terahertz spectroscopy have revealed large signals from water, which have been interpreted with different, sometimes competing, theoretical models. Here, we show that the non-linear transmission of liquid water at ∼1 THz is equal at 21 and 4 °C, thus suggesting that the most appropriate microscopic models should depend weakly on temperature. Among the different mechanisms proposed to date, the resonant reorientation of hydrogen-bonded water molecules might be the most appropriate to describe all of the currently available experimental results.