Pressure induced enhancement of the magnetic ordering temperature in rhenium(IV) monomers

Christopher H. Woodall; Gavin A. Craig; Alessandro Prescimone; Martin Misek; Joan Cano; Juan Faus; Michael R. Probert; Simon Parsons; Stephen Moggach; José Martínez-Lillo; Mark Murrie; Konstantin V. Kamenev; Euan K. Brechin

doi:10.1038/ncomms13870

Nature Communications (Dec 2016)

Pressure induced enhancement of the magnetic ordering temperature in rhenium(IV) monomers

Christopher H. Woodall,
Gavin A. Craig,
Alessandro Prescimone,
Martin Misek,
Joan Cano,
Juan Faus,
Michael R. Probert,
Simon Parsons,
Stephen Moggach,
José Martínez-Lillo,
Mark Murrie,
Konstantin V. Kamenev,
Euan K. Brechin

Affiliations

Christopher H. Woodall: EaStCHEM School of Chemistry and Centre for Science at Extreme Conditions, The University of Edinburgh
Gavin A. Craig: WestCHEM School of Chemistry, University of Glasgow, University Avenue
Alessandro Prescimone: EaStCHEM School of Chemistry and Centre for Science at Extreme Conditions, The University of Edinburgh
Martin Misek: School of Physics and Centre for Science at Extreme Conditions, The University of Edinburgh
Joan Cano: Departament de Química Inorgànica/Instituto de Ciencia Molecular (ICMol), Universitat de València
Juan Faus: Departament de Química Inorgànica/Instituto de Ciencia Molecular (ICMol), Universitat de València
Michael R. Probert: School of Chemistry, Newcastle University
Simon Parsons: EaStCHEM School of Chemistry and Centre for Science at Extreme Conditions, The University of Edinburgh
Stephen Moggach: EaStCHEM School of Chemistry and Centre for Science at Extreme Conditions, The University of Edinburgh
José Martínez-Lillo: EaStCHEM School of Chemistry and Centre for Science at Extreme Conditions, The University of Edinburgh
Mark Murrie: WestCHEM School of Chemistry, University of Glasgow, University Avenue
Konstantin V. Kamenev: School of Engineering and Centre for Science at Extreme Conditions, The University of Edinburgh
Euan K. Brechin: EaStCHEM School of Chemistry and Centre for Science at Extreme Conditions, The University of Edinburgh

DOI: https://doi.org/10.1038/ncomms13870
Journal volume & issue: Vol. 7, no. 1
pp. 1 – 7

Abstract

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Materials that demonstrate long-range magnetic order are synonymous with information storage. Here, the authors report the effect of pressure on two mononuclear rhenium compounds that exhibit long-range magnetic order under ambient conditions via a spin canting mechanism, whereTcis proportional to pressure.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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