Nature Communications (Dec 2017)
Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides
- William E. Gent,
- Kipil Lim,
- Yufeng Liang,
- Qinghao Li,
- Taylor Barnes,
- Sung-Jin Ahn,
- Kevin H. Stone,
- Mitchell McIntire,
- Jihyun Hong,
- Jay Hyok Song,
- Yiyang Li,
- Apurva Mehta,
- Stefano Ermon,
- Tolek Tyliszczak,
- David Kilcoyne,
- David Vine,
- Jin-Hwan Park,
- Seok-Kwang Doo,
- Michael F. Toney,
- Wanli Yang,
- David Prendergast,
- William C. Chueh
Affiliations
- William E. Gent
- Department of Chemistry, Stanford University
- Kipil Lim
- Department of Materials Science and Engineering, Stanford University
- Yufeng Liang
- The Molecular Foundry, Lawrence Berkeley National Laboratory
- Qinghao Li
- The Advanced Light Source, Lawrence Berkeley National Laboratory
- Taylor Barnes
- The Molecular Foundry, Lawrence Berkeley National Laboratory
- Sung-Jin Ahn
- Energy Lab, Samsung Advanced Institute of Technology, 130, Samsung-ro
- Kevin H. Stone
- Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory
- Mitchell McIntire
- Department of Computer Science, Stanford University
- Jihyun Hong
- Department of Materials Science and Engineering, Stanford University
- Jay Hyok Song
- Energy1lab, Samsung SDI, 130, Samsung-ro
- Yiyang Li
- Department of Materials Science and Engineering, Stanford University
- Apurva Mehta
- Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory
- Stefano Ermon
- Department of Computer Science, Stanford University
- Tolek Tyliszczak
- The Advanced Light Source, Lawrence Berkeley National Laboratory
- David Kilcoyne
- The Advanced Light Source, Lawrence Berkeley National Laboratory
- David Vine
- The Advanced Light Source, Lawrence Berkeley National Laboratory
- Jin-Hwan Park
- Energy Lab, Samsung Advanced Institute of Technology, 130, Samsung-ro
- Seok-Kwang Doo
- Energy Lab, Samsung Advanced Institute of Technology, 130, Samsung-ro
- Michael F. Toney
- Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory
- Wanli Yang
- The Advanced Light Source, Lawrence Berkeley National Laboratory
- David Prendergast
- The Molecular Foundry, Lawrence Berkeley National Laboratory
- William C. Chueh
- Department of Materials Science and Engineering, Stanford University
- DOI
- https://doi.org/10.1038/s41467-017-02041-x
- Journal volume & issue
-
Vol. 8,
no. 1
pp. 1 – 12
Abstract
Lithium ion battery electrodes employing anion redox exhibit high energy densities but suffer from poor cyclability. Here the authors reveal that the voltage of anion redox is strongly affected by structural changes that occur during battery cycling, explaining its unique electrochemical properties.
