Acta Crystallographica Section E (Sep 2010)

Racemic tricarbonyl[(4a,5,6,7,8,8a-η)-2-phenyl-3,4-dihydro-2H-1-benzopyran]chromium(0)

  • Johannes H. van Tonder,
  • Barend C. B. Bezuidenhoudt,
  • J. Marthinus Janse van Rensburg

DOI
https://doi.org/10.1107/S1600536810031028
Journal volume & issue
Vol. 66, no. 9
pp. m1086 – m1086

Abstract

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The title compound, [Cr(C15H14O)(CO)3], displays a distorted envelope configuration of the dihydropyrane ring. The dihedral angle between the phenyl and phenylene rings is 50.63 (4)°. The Cr0 atom is coordinated by three CO groups and the phenylene ring of the flavan ligand in an η6 mode, with a common arene-to-metal distance