Rheological Behavior of Alumina Ceramic Pastes

Abstract

The rheological behavior of ceramic oxide hydroxide alumina pastes with high solid loading is investigated. In order to enable an adequate and experimentally rheological characterization, the measurements are carried out with a Rheostress viscometer under isothermal conditions. Various compositions of a commercial AlOOH powder and binder mixture are investigated. We discuss the variation of loss modulus G′, storage modulus G″, apparent and complex viscosities η, η* as function of frequency and shear rate. The solid phase used here is the boehmite; the most important precursor for the γ-Al2O3 phase for several applications such as catalysts or functional layers of ceramics. Solid phase compositions used are justified by the applications of boehmite in the manufacturing of catalytic materials. A transition zone that appears at a concentration of 55 %wt of the solid phase (Pural) and at which the rheological behavior changes from viscoelastic to elastic is observed. This transition is of a importance as far as ceramic manufacturing is concerned.

Keywords

• alumina
• paste
• herschel-bulkley model