The self-assembly of rod-coil block copolymer and homopolymer blends in solution(刚柔嵌段共聚物与均聚物在溶液中的自组装)

ZHANGRuifen(张瑞芬); WANGSiwen(王丝雯); HELinli(何林李)

doi:10.3785/j.issn.1008-9497.2014.03.013

Zhejiang Daxue xuebao. Lixue ban (May 2014)

The self-assembly of rod-coil block copolymer and homopolymer blends in solution(刚柔嵌段共聚物与均聚物在溶液中的自组装)

ZHANGRuifen(张瑞芬),
WANGSiwen(王丝雯),
HELinli(何林李)

Affiliations

ZHANGRuifen(张瑞芬): College of Physics and Electronic Information, Wenzhou University, Wenzhou 325035, Zhejiang Province, China(温州大学物理与电子信息工程学院，浙江　温州　325035)
WANGSiwen(王丝雯): College of Physics and Electronic Information, Wenzhou University, Wenzhou 325035, Zhejiang Province, China(温州大学物理与电子信息工程学院，浙江　温州　325035)
HELinli(何林李): College of Physics and Electronic Information, Wenzhou University, Wenzhou 325035, Zhejiang Province, China(温州大学物理与电子信息工程学院，浙江　温州　325035)

DOI: https://doi.org/10.3785/j.issn.1008-9497.2014.03.013
Journal volume & issue: Vol. 41, no. 3
pp. 303 – 306

Abstract

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采用耗散粒子动力学(DPD)模拟方法研究了向刚柔嵌段共聚物溶液中掺入均聚物的自组装行为，当掺入的刚性棒或柔性高分子链浓度不同时，由于刚性棒的取向性及柔性高分子链构象熵的变化，观察到了一系列丰富的相结构，如双层柱状、层状、层柱共混状、反转的空心柱状等.少量的均聚物和刚柔嵌段共聚物溶液共混后的密度分布显示，均聚物聚集于胶束相结构的中心.

Published in Zhejiang Daxue xuebao. Lixue ban

ISSN: 1008-9497 (Print)
Publisher: Zhejiang University Press
Country of publisher: China
LCC subjects: Science: Mathematics: Instruments and machines: Electronic computers. Computer science; Science: Physics
Website: https://www.zjujournals.com/sci/EN/1008-9497/home.shtml

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