Scientific Reports (Jun 2024)

Predictive modeling of pH on the transport of Co(II) Ions from aqueous solutions through supported ceramic polymer membrane

  • A. T. Kassem,
  • M. M. S. Ali,
  • N. M. Sami

DOI
https://doi.org/10.1038/s41598-024-63854-7
Journal volume & issue
Vol. 14, no. 1
pp. 1 – 16

Abstract

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Abstract Optimal pH is essential for efficient cobalt extraction from polymeric membrane systems, with D2EHPA used as an extractant for Co(II) at pH 80%. Depending on the functional group of (C4H10N2), the optimal pH for separation was 9.8. The study revealed that pKa value was calculated to predict the ideal pH, and its value was 9.73, which is nearly to the pH, since the pH of the strip concentration and the properties of the membrane affect the extraction of cobalt at 30 °C. The partition ratio indicates the high distribution of the extract in supported ceramic polymer membrane (SCPM). The ceramic component provides mechanical strength and rigidity to the overall membrane structure, allowing it to withstand high pressures and temperatures during operation Study various factors such as the effect of pH on the ionization of the extract; effect of pH on band ionization; effect of pH on the temperature in the extract, effect of pH on the solute, effect of the band at different pH ranges and a comparison was made between the predictive model and experimental data that was proven through mathematical modeling using the MATLAB program.

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