UV/VIS-Spectroscopic Inline Measurement for the Detection of Fouling Processes during the Polymerization of N-Vinylpyrrolidone

Abstract

With the goal to better process the monitoring of occurring fouling, a backscatter probe was developed to perform in-line measurements in a half-shell reactor during the reaction of N-vinylpyrrolidone (NVP) to polyvinylpyrrolidone (PVP). The measurement technique detects the changes of bands in the UV range, which allows a direct correlation with the concentration. Thus, the measured absorbance signal allows a conclusion on the accumulation of fouling in the reactor and on changes in the conversion at the measurement location.

Keywords

• process engineering
• UV/VIS spectroscopy
• optical measurement
• highly sensitive detector
• radical polymerization
• N-Vinylpyrrolidone