A gradient oxy-thiophosphate-coated Ni-rich layered oxide cathode for stable all-solid-state Li-ion batteries

Jianwen Liang; Yuanmin Zhu; Xiaona Li; Jing Luo; Sixu Deng; Yang Zhao; Yipeng Sun; Duojie Wu; Yongfeng Hu; Weihan Li; Tsun-Kong Sham; Ruying Li; Meng Gu; Xueliang Sun

doi:10.1038/s41467-022-35667-7

Nature Communications (Jan 2023)

A gradient oxy-thiophosphate-coated Ni-rich layered oxide cathode for stable all-solid-state Li-ion batteries

Jianwen Liang,
Yuanmin Zhu,
Xiaona Li,
Jing Luo,
Sixu Deng,
Yang Zhao,
Yipeng Sun,
Duojie Wu,
Yongfeng Hu,
Weihan Li,
Tsun-Kong Sham,
Ruying Li,
Meng Gu,
Xueliang Sun

Affiliations

Jianwen Liang: Department of Mechanical and Materials Engineering, University of Western Ontario
Yuanmin Zhu: Research Institute of Interdisciplinary Science & School of Material Science and Engineering, Dongguan university of technology
Xiaona Li: Department of Mechanical and Materials Engineering, University of Western Ontario
Jing Luo: Department of Mechanical and Materials Engineering, University of Western Ontario
Sixu Deng: Department of Mechanical and Materials Engineering, University of Western Ontario
Yang Zhao: Department of Mechanical and Materials Engineering, University of Western Ontario
Yipeng Sun: Department of Mechanical and Materials Engineering, University of Western Ontario
Duojie Wu: Department of Materials Science and Engineering, Southern University of Science and Technology
Yongfeng Hu: Canadian Light Source, 44 Innovation Boulevard
Weihan Li: Department of Mechanical and Materials Engineering, University of Western Ontario
Tsun-Kong Sham: Department of Chemistry, University of Western Ontario
Ruying Li: Department of Mechanical and Materials Engineering, University of Western Ontario
Meng Gu: Department of Materials Science and Engineering, Southern University of Science and Technology
Xueliang Sun: Department of Mechanical and Materials Engineering, University of Western Ontario

DOI: https://doi.org/10.1038/s41467-022-35667-7
Journal volume & issue: Vol. 14, no. 1
pp. 1 – 12

Abstract

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Layered oxide cathode active materials suffer from interfacial structural instability when coupled with sulfide solid-state electrolytes. Here, the authors propose a gradient coating with a lithium oxythiophosphate layer that can stabilize the cathode|solid-state electrolyte interface.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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